Thermite welding (TW) (sometimes called thermit welding) is a process which joins metals by heating them with
super heated liquid metal from a chemical reaction between a metal oxide and
aluminum or other reducing agent, with or without the application of pressure.
Filler metal is obtained from the liquid metal.
b. The heat for welding is obtained from an exothermic reaction or chemical
change between iron oxide and aluminum. This reaction is shown by the following
formula:
8A1 + 3fe304 = 9FE +
4A1203 + Heat
The temperature resulting from this reaction is approximately 4500°F
(2482°C).
c. The super heated steel is contained in a crucible located immediately above
the weld joint. The exothermic reaction is relatively slow and requires 20 to 30
seconds, regardless of the amount of chemicals involved. The parts to be welded
are aligned with a gap between them. The super heated steel runs into a mold
which is built around the parts to be welded. Since it is almost twice as hot as
the melting temperature of the base metal, melting occurs at the edges of the
joint and alloys with the molten steel from the crucible. Normal heat losses
cause the mass of molten metal to solidify, coalescence occurs, and the weld is
completed. If the parts to be welded are large, preheating within the mold
cavity may be necessary to bring the pats to welding temperature and to dry out
the mold. If the parts are small, preheating is often eliminated. The thermit
welding process is applied only in the automatic mode. Once the reaction is
started, it continues until completion.
d. Themite welding utilizes gravity, which causes the molten metal to fill the
cavity between the parts being welded. It is very similar to the foundry
practice of pouring a casting. The difference is the extremely high temperature
of the molten metal. The making of a thermit weld is shown in figure 6-12.
When the filler metal has cooled, all unwanted excess metal may be removed by
oxygen cutting, machining, or grinding. The surface of the completed weld is
usually sufficiently smooth and contoured so that it does not require additional
metal finishing.

THERMITE WELDING EQUIPMENT (TW)
a. General. Thermite material is a mechanical mixture of metallic
aluminum and processed iron oxide. Molten steel is produced by the thermite
reaction in a magnesite-lined crucible. At the bottom of the crucible, a
magnesite stone is burned, into which a magnesite stone thimble is fitted. This
thimble provides a passage through which the molten steel is discharged into the
mold. The hole through the thimble is plugged with a tapping pin, which is
covered with a fire-resistant washer and refractory sand. The crucible is
charged by placing the correct quantity of thoroughly mixed thermit material in
it. In preparing the joint for thermite welding, the parts to be welded must be
cleaned, alined, and held firmly in place. If necessary, metal is removed from
the joint to permit a free flow of the thermite metal into the joint. A wax
pattern is then made around the joint in the size and shape of the intended
weld. A mold made of refractory sand is built around the wax pattern and joint
to hold the molten metal after it is poured. The sand mold is then heated to
melt out the wax and dry the mold. The mold should be properly vented to permit
the escape of gases and to allow the proper distribution of the thermite metal at
the joint. A thermite welding crucible and mold is shown in figure 5-41.

THERMITE WELDING USE (TW)
Thermite Welding has been successfully used for many years in the Railroad industry
to weld rails together. Equipment similar to the above sketches is set up at the welding
joint. After the process has been completed and the weld has cooled enough, the thermite fixture is
removed. The slag is chipped off and the excess weld is ground off to conform with the
shape of the rails.
Watch a video of a rail welding crew using thermite welding here:
Thermite Rail Welding