Characteristics
Aluminum alloys are used in engineering design chiefly for their light weight, high strength to weight ratio, corrosion resistance,
and relatively low cost. Aluminum is the most widely distributed of the elements, except for oxygen, nitrogen, and silicon. Aluminum
alloys weigh about 0.1 pound per cubic inch. This is about one third the weight of iron at 0.28 pounds and copper at 0.32, is slightly
heavier than magnesium at 0.066, and somewhat lighter than titanium at 0.163.
In its commercially pure state, aluminum is a relatively
weak metal, having a tensile strength of approximately 13,000 PSI. However, with the addition of small amounts of alloying elements
such as manganese, silicon, copper, magnesium, or zinc, and with the proper heat treatment or cold working, the tensile strength
of aluminum can be made to approach 100,000 PSI.
Corrosion resistance of aluminum may be attributed
to its self-healing nature, in which a thin,
invisible skin of aluminum oxide forms when the
metal is exposed to the atmosphere. Pure aluminum
will form a continuous protective oxide film - i.e.,
corrode uniformly - while high-strength alloyed
aluminum will sometimes become pitted as a result
of localized galvanic corrosion at sites of
alloying-constituent concentration.
Aluminum is easily fabricated - one of its
most important assets. It can be cast by any
method known to the foundryman; it can be rolled’
to any thickness, stamped, hammered, forged, or
extruded. Aluminum is readily turned, milled,
bored, or machined at the maximum speeds of
which most machines are capable, and is adaptable
to automatic screw machine processing.
Aluminum can be joined by almost any method -
riveting, gas, arc, or resistance welding; brazing;
and adhesive bonding.
Many aluminum alloys have wide property
ranges as a result of tempers attainable through
treatment, both thermal and mechanical. With
these wide ranges, much overlapping of properties
exists among the various alloys thus making
available a large number of compositions from
which to choose. This increased selection provides
for a greater latitude in the choice of
fabricating techniques, and permits the selection
of the most economical method.
CLASSES OF ALUMINUM AND ALUMINUM ALLOY
Types Available Aluminum is available
in various compositions, including “pure” metal,
alloys for casting, and alloys for the manufacture
of wrought products. (Alloys for casting are
normally different from those used for rolling,
forging, and other working.) All types are produced
in a wide variety of industrial shapes and forms.
"Pure" Aluminum "Pure" Aluminum. Pure aluminum is available
both as a high-purity metal and as a commercially
pure metal. Both have relatively low
strength, and thus have limited utility in engineering
design, except for applications where good
electrical conductivity, ease of fabrication, or
high resistance to corrosion are important. Pure
aluminum is not heat treatable. However, its
mechanical properties may be varied by strain
hardening (cold work). Pure aluminum exhibits
poor casting qualities; it is employed chiefly in
wrought form. Commercially pure aluminum is
available as foil, sheet and plate, wire, bar, rod,
tube, and as extrusions and forgings.
Casting Alloys The aluminum alloys specified
for casting purposes contain one or more
alloying elements, the maximum of any one element
not exceeding 12 percent. Some alloys are
designed for use in the as-cast condition; others
are designed to be heat treated to improve their
mechanical properties and dimensional stability.
High strength, together with good ductility, can
be obtained by selection of suitable composition
and heat treatment.
Aluminum casting alloys are usually identified
by arbitrarily selected, commercial designations
of two- and three-digit numbers. These designations
are sometimes preceded by a letter to indicate
that the original alloy of the same number
has been modified.
Wrought Alloys Most aluminum alloys
used for wrought products contain less than 7
percent of alloying elements. By the regulation
of the amount and type of elements added, the
properties of the aluminum can be enhanced and
its working characteristics improved. Special
compositions have been developed for particular
fabrication processes such as forging and extrusion.
As with casting alloys, wrought alloys are
produced in both heat-treatable and non-heat-treatable
types. The mechanical properties of the
"non-heat-treatable" type may be varied by strain-hardening,
or by strain-hardening followed by partial
annealing. The mechanical properties of the
heat-treatable types may be improved by quenching
from a suitable temperature and then aging.
With the heat-treatable alloys, especially desirable
properties may be obtained by a combination
of heat treatment and strain-hardening.
ALUMINUM ASSOCIATION DESIGNATIONS FOR ALLOY GROUPS
Aluminum - 99.00% minimum and greater . . . . . . . . . . . . . . 1xxx
Major Alloying Elements
Copper. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2XXX
Aluminum Manganese . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3XXX
Silicon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4XXX
Magnesium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5XXX
Alloying Magnesium and Silicon . . . . . . . . . . . . . . . . . . . . . . . .6XXX
Zinc . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7XXX
Other Elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8XXX
Unused Series . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9XXX
The principal wrought forms of aluminum alloys
are plate and sheet, foil, extruded shapes, tube,
bar, rod, wire and forgings.
Wrought aluminum alloys are designated by
four-digit numbers assigned by the Aluminum
Association. The first digit indicates the alloy
group; the second digit indicates modifications
of the original alloy (or impurity limits); the last
two digits identify the aluminum alloy or indicate
the aluminum purity. The system of designating
alloy groups is shown in figure 2. Experimental
alloys are also designated in accordance with
this system, but their numbers are prefixed by
the letter X. This prefix is dropped when the
alloy becomes standard.
Welding Aluminum
The welding of aluminum is common practice
in industry because it is fast, easy, and
relatively inexpensive. It is especially
useful in making leakproof joints in thick or thin
metal, and can be employed with either wrought or
cast aluminum, or a combination of both. Not all
compositions of aluminum alloy are suitable
for welding, and not all methods of welding
can be used with them. The suitability for
welding and the relative weldability of some
aluminum alloys are given in tables 1 and 2.
Characteristics and Uses of Wrought Aluminum Alloys

Characteristics and Uses of Wrought Aluminum Alloys

Weldability Ratings for Cast and Wrought Aluminum

The welding of aluminum consists of fusing
the molten parent metal together (with or without
the use of filler metal), or of upsetting by pressure
(with or without heat generated by the electrical
resistance of the metal).
A wide variety of welding methods are employed
in the welding of aluminum. These include torch
(gas), metal-arc, carbon-arc, tungsten-arc, atomic hydrogen,
and electric-resistance welding. The
equipment used is the same, except that it must
be modified in some instances to permit slight
changes in welding practices.
The corrosion-resistant oxide film that protects
aluminum, deters the “wetting” action required
for coalescence of the metals during welding. To
effect a successful weld, this tough coating must
be removed (and prevented from reforming) either
mechanically, chemically, or electrically. Mechanical
removal consists of abrading with a sander,
stainless-steel wool, or some such means. Such
a method is fast, but it is a manual operation,
and should be reserved for comparatively small
amounts of work.
Chemical removal is accomplished
with fluxes that dissolve and float the
oxides away. It is the most practical means of
penetrating the glass-like oxide coating, and is
well suited to the production of larger amounts of
work. Its drawbacks include the danger of leaving
voids or blow holes as a result of entrapment of
slag, and the need for cleaning operations to remove
any remaining corrosive flux
Electrical removal, used in some forms of arc welding, consists
of the application of a reverse polarity (work
negative) of welding current which loosens the
oxide by electron emission. The reforming of
oxides is prevented during welding and cooling of
the weld by the cover of flux or by the use of
inert gases to blanket the weld area.
The good thermal conductivity of aluminum
allows the heat of welding to spread rapidly from
the weld zone; this can result in a loss in strength
in work-hardened or heat-treated alloys through
annealing. It can also cause buckling or total
collapse of the parent metal if the metal is not
supported properly during welding. The good electrical
conductivity necessitates the use of higher
currents in resistance welding.
The low melting point of aluminum, in the range
of 900°F (482°C) to 1216°F (658°C), increases
the need for care in preventing the melting away
of the metal parts that are to be welded. Since
aluminum gives no visual indication of having
attained welding temperature (that is, it does not
become red, as does steel), the temperature has
to be measured by the physical condition of the
aluminum instead of its appearance. Aluminum
tends to simply run like water when it reaches
its melting point.
In welding applications where a considerable
amount of general heating can be tolerated and
where an easily finished bead is desired, gas
welding is preferred. However, where minimum
general heating, absence of flux, and very good
properties are requirements, one of the types of
inert-gas-shielded arc-welding method should be
selected.
Gas welding is commonly done with oxypropane or
oxyacetylene mixtures. The oxyacetylene flame
is used most widely because of its availability for
welding other metals. Butt, lap, and fillet welds
are made in thickness of metal from 0.040 up to
1 inch.
Carbon-arc welding is an alternative method for
joining material about 1/16 to 1/2 inch thick. The
carbon arc affords a more concentrated heat source
than a gas torch flame. Hence, it permits faster
welding with less distortion. Soundness of welds
is excellent and is comparable to that of good
gas welding.
Gas metal-arc welding (GMAW) is especially suitable for
heavy material. Welds in plate 2 1/2 inches thick
are made satisfactorily by this method. Unsound
joints are likely to appear in gas-metal-arc-welded
material which is less than 5/64 inch thick. Weld
soundness and smoothness of the surface are nearly
as good as other arc-welding methods. This method
has gained popularity as it uses no flux, but does
employ a gas shielding of argon or helium, or a
combination of both. This method also has a high
production rate and reduces labor costs.
Shielding-metal-arc-welding (SMAW) is another
electric arc method of welding aluminum. This
method is difficult to master and often leaves
slag inclusions in the deposited weld. This method
of welding aluminum is more suitable for small repairs.
Gas tungsten-arc welding (GTAW) has two distinct advantages
over some other forms of fusion welding; no flux
is needed, and welds can be made with almost
equal facility in the flat, vertical, or overhead
positions. The advantages are the result of the
ability to concentrate the heat, and the blanketing
of the area with inert gas (argon or helium). The
process can be used for either manual or automatic
welding on metals 0.05 inch thick or thicker.
Resistance welding is especially useful for
joining high-strength aluminum alloy sheet with
practically no loss of strength. It includes three
main types of processes; spot welding, seam or
line welding, and butt or flash welding. The type
adopted for assembly operations depends mainly
on the form of material to be joined. Spot welding
is widely used to replace riveting; it joins sheet
structures at intervals as required. Seam welding
is merely spot welding with the spots spaced so
closely that they overlap to produce a gas-tight
joint. Flash welding, sometimes classified as a
resistance welding process, differs from spot
welding in that it is used only for butt joints; the
metal is heated for welding by establishing an
arc between the ends of the two pieces to be
joined.
Brazing Aluminum
Brazing differs from welding, in
that filler metal is melted and flowed into the
joint with little or no melting of the parent metal.
(The brazing alloy melts at about 100°F (38°C)
below that of the parent metal.) As a result, brazing
is ideally suited to the joining of thinner material.
It is also lower in cost than welding, has
neater appearance, requires little finishing, and
is suited to mass production methods. In addition,
the corrosion resistance of brazed aluminum joints
compares favorably, in general, to welded joints
in the same alloy because, unlike solder, the
filler metal is an aluminum alloy.
The strength of a brazed joint is equivalent to
that of the metal in the annealed condition. However,
in some instances where an age-hardening
alloy is used, the mechanical properties of the
metal can be enhanced by treatment. For example,
alloy 6061 (61S), when quenched from the brazing
operation and then artificially aged, will exhibit
a tensile strength of approximately 45,000 psi, a
yield strength of 40,000 psi, and an elongation in
two inches of 9 percent. Brazeable alloys are available in plate, sheet,
tube, rod, bar, wire, and shapes. They are generally
confined to alloys 1100, 3003, and 6061.
Soldering Aluminum
Aluminum can be joined to aluminum and to other
solderable metals by means of a soldering iron or
torch, and an alloy of approximately
60 percent tin and 40 percent zinc.
This method of joining is satisfactory for
such applications as indoor electrical joints; it
is not recommended for joining structural members
or for use in moist or corrosive atmospheres because
of the low mechanical properties of the
solder and the difference in electrical potential
between the solder and the aluminum.
The soldering of aluminum is similar to other
forms of soldering, but it is somewhat more difficult
to perform because of the high thermal conductivity
of the aluminum and the presence of a
tough oxide film. The thermal conductivity increases
the problem of maintaining sufficient heat
at the working area to melt the solder. (Aluminum
solder melts at 550°F (288°C) to 700°F ( 371°C)
as compared with 375°F (190°C) to 400°F (204°C)
for most other solders.) Thus only small parts (20
square inches or less) which can be preheated,
are suitable for soldering with an iron; larger parts
require the use of a torch to concentrate sufficient
heat.
The tough oxide film may be removed by dissolving
it with a flux or by abrading it with a
soldering iron or other mechanical means. In each
instance, the working area must be kept covered
with fluid flux or molten solder to exclude oxygen
from the surface and to prevent the formation of a
new oxide coating. However, after the surfaces
are tinned, they may be joined in the usual manner.